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Titanium grades · Grade 4 · strongest CP grade

Grade 4 Titanium

Grade 4 is the strongest of the four commercially pure titanium grades at 550 MPa minimum tensile — about 60% above Grade 2, achieved through oxygen and iron control rather than alloying. It is specified where a CP grade's corrosion behaviour is wanted together with more strength, most notably for dental milling discs.

Square-cut corner of a titanium plate
CP titanium plate, square-cut. Grade 4 is not visually distinguishable from Grade 2 — illustrative photograph.

What Grade 4 is

Grade 4 (UNS R50700) is still unalloyed titanium. Nothing is added to it: it reaches 550 MPa by allowing more oxygen (up to 0.40%) and iron (up to 0.50%) than Grade 2 does. Oxygen is an interstitial strengthening element in titanium, and this is the top of the range before the metal loses too much ductility to be useful.

The consequence worth understanding before specifying it: Grade 4 costs formability for strength. Minimum elongation drops to 15% against Grade 2's 20%, so severe cold forming is harder. It remains fully weldable with the same discipline as Grade 2.

Chemical composition

Grade 4 titanium — composition limits (ASTM B265 / B348, weight percent, maximum)
ElementLimit
Nitrogen, N0.05
Carbon, C0.08
Hydrogen, H0.015
Iron, Fe0.50
Oxygen, O0.40
Titanium, TiBalance

Composition limits and mechanical values below are the published requirements of the referenced ASTM specification. They state what the standard requires — they are not the measured result of any particular heat or lot, and they are not a guarantee of what a given order will return.

Mechanical properties

Grade 4 titanium — minimum mechanical properties per ASTM B265 (annealed)
PropertyMinimum value
Tensile strength550 MPa (80 ksi)
Yield strength, 0.2% offset483 MPa (70 ksi)
Elongation in 2 in / 50 mm15%
Reduction of area (bar, ASTM B348)25%
Typical density4.51 g/cm³ (reference value)

Values are annealed-condition minimums. Cold-worked material reaches higher strength with lower ductility; cold-worked supply is quoted to the specific requirement.

Grade 4 in dental CAD/CAM

The single largest use of Grade 4 that buyers enquire about is the milling disc — the blank stock that dental laboratories machine into implant superstructures, abutments and frameworks on a CAD/CAM mill. Grade 4 is chosen there because it delivers high strength from an unalloyed chemistry: no vanadium, and a surface that behaves predictably in the oral environment.

Two boundaries are worth stating plainly. First, this page describes the material standard and how the grade is used in the sector — it is not a medical-device claim. Second, whether we can supply disc stock in a given diameter and thickness, and to which certificate, is confirmed on inquiry rather than asserted here.

Standards referenced in medical contexts — ASTM F67 for unalloyed titanium and ASTM F136 for Ti-6Al-4V ELI — are material specifications. Compliance of a finished device is the manufacturer's own regulatory matter, and we do not claim certification of any finished product.

Choosing between Grade 2, Grade 4 and Grade 23 when strength matters

Strength-driven selection between three grades
If the requirement is…Usually specifiedWhy
Corrosion duty plus moderate loads, easiest formingGrade 2Highest ductility of the three and usually the lowest cost level
More strength, still unalloyed, no vanadiumGrade 4550 MPa from interstitial strengthening; the dental-milling standard choice
Highest strength with toughness and low interstitialsGrade 23 (ELI)Alloyed with aluminium and vanadium, tighter interstitials, and a different cost level

A detailed side-by-side of the two extremes is given in Grade 2 vs Grade 5, and Grade 23 with its interstitial control is covered on the Grade 23 page.

Forms we quote in Grade 4

  • Plate and sheet — the most commonly enquired Grade 4 form; see plate & sheet.
  • Machined parts — components produced to drawing in Grade 4; see machined parts.
  • Disc and block stock — supply availability, size range and certificate type are confirmed on inquiry.

Availability, size range and lead time for a specific grade and form are confirmed in the quotation — please contact us for confirmation.

Need Grade 4 plate or disc stock? Send diameter, thickness, standard and quantity and we will confirm what can be quoted.

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Request Grade 4 titanium

State the form, dimensions, quantity and the standard your drawing references. If you are deciding between Grade 2, Grade 4 and Grade 23, describe the load case and the environment and we will give a view.

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Frequently asked questions

Why is Grade 4 stronger than Grade 2 if neither has alloying elements?
Because of interstitials. Grade 4 permits more oxygen and iron than Grade 2, and both strengthen titanium by distorting the crystal lattice. Nothing is alloyed in the usual sense — the difference is what is allowed to remain.
Can Grade 4 be cold formed?
Less readily than Grade 1 or Grade 2. Minimum elongation is 15%, so tight bends and deep draws are harder and may need intermediate annealing. For severe forming Grade 1 is normally the better choice.
Is Grade 4 used for dental implants?
Grade 4 is widely used for dental implant components and for CAD/CAM milling of superstructures. We supply material; we are not a medical device manufacturer and make no device claim.
What standards cover Grade 4?
ASTM B265 covers Grade 4 plate, sheet and strip; ASTM B348 covers bar. ASTM F67 covers unalloyed titanium for surgical implant applications and is referenced for that sector.
Is Grade 4 weldable?
Yes, with the same cleanliness and shielding discipline required for any titanium weld. The joint efficiency achieved is a function of procedure, not of the grade alone.

Titanium stock supply & custom machining

Titanium mill products are available from stock across a broad range of grades and sizes through our Baoji manufacturing and supply network. Send your exact grade, standard, dimensions and quantity to confirm the stock match, documents and dispatch date.

Custom titanium machined parts: 3–30 days. Lead time depends on drawing complexity, quantity, tolerance and inspection requirements. The production start date is agreed with the order; international transit is additional.

Enquiries welcome from Europe, the Americas and the Middle East. Include your destination country, units, delivery terms and documentation requirements.